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Q.

Match the half-life of the reaction in List-I with the integrated rate equation in List-II (a = initial concentration of reactant and a-x = concentration of reactant at time ‘t’.)

 List-I List-II
P)t1/2=0.586ka1)k=xt
Q)t1/2=0.693k2)k=1t[1ax1a]
R)t1/2=a2k3)k=2t[aax]
S)t1/2=1ka4)k=2.303tlogaax
  5)k=2t[1ax1a]

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a

P3;Q4;R1;S2

b

P2;Q3;R1;S2

c

P3;Q2;R4;S5

d

P5;Q4;R1;S2

answer is B.

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Detailed Solution

ANS-B
SOL-  POrder  of  the  reaction=12
  Q1storderreaction
 Rzeroorderreaction
 S2ndorderreaction

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