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Q.

Match the isostructural pairs.

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a

IF6+

,

ClF4+

,

SnCl5

,

ICl3

,

ClF2

,

XeF4

b

SF4

,

PCI5

,

ICl3

,

I3-

,

ICI-4

,

PCI-6

answer is F, E, D, C, B, A.

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Detailed Solution

The SF4is the isostructural pairs of ClF4+ as both have trigonal bipyramidal shape.

The PCI5is the isostructural pairs of SnCl5 as both have trigonal bipyramidal shape.

The ICl3is the isostructural pairs of ICl3 as both have trigonal bipyramidal shape with a T-shaped molecular shape.

The I3-is the isostructural pairs of ClF2 as both have molecular geometry is linear

The ICI-4is the isostructural pairs of XeF4 as there are total of 36 valence electrons.

The PCI-6is the isostructural pairs of IF6+ as its shape is an octahedral

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