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Q.

Match the items of Column I and Column II on the basis of data given below.
        EF2/F=2.87V,ELi+/Li=3.5V,EAu3+/Au=1.4V,EBr2/Br=1.09V
 

 Column I Column II
AF21.Metal is the strongest reducing agent.
BLi2.Metal ion which is the weakest oxidising agent.
CAu3+3.Non-metal which is the best oxidising agent.
DBr-4.Unreactive metal.
EAu5.Anion that can be oxidised by Au3+.
FLi+6.Anion which is the weakest reducing agent.
GF-7.Metal ion which is an oxidising agent.

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a

A - 3 ; B - 1 ; C - 7 ; D - 5 ; E - 4 ; F - 2 ; G - 6 

b

A - 3 ; B - 1 ; C - 5 ; D - 7 ; E - 2 ; F - 4 ; G - 6 

c

A - 1 ; B - 3 ; C - 5 ; D - 7 ; E - 4 ; F - 2 ; G - 6 

d

A - 3 ; B - 1 ; C - 5 ; D - 7 ; E - 4 ; F - 6 ; G - 2

answer is B.

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Detailed Solution

 A.  (3)      B.  (1)      C.  (7)  D. (5)  E.  (4)      F.  (2)      G. (6)    
A. F2 it a non-metal and best oxidising agent because SRP of F2 is + 2.87 V.
B. Li is a metal and strongest reducing agent because SRP of Li is - 3.05 V.
C. Au3+ is a metal ion which is an oxidising agent as SRP of Au3+ is +1.40 V.
D. Br- is an anion that can be oxidised by Au3+ as Au3+ (Eo = 1.40) is greater than Br- (Eo = 1.09 V).
E. Au is an un reactive metal.
F. Li+ is a metal ion having least value of SRP (-3.05 V), hence it is the weakest oxidising agent.
G. F- is an anion which is the weakest reducing agent as F- / F2 has low oxidation potential (-2.87 V).

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