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Q.

Match the lists I and II and pick the correct matching from the codes given below.
 

List-I                               List-II
 

(complex)                  (Structure and
                                     magnetic moment)
a) [Ag(CN)2]–        1) square planar and 1.73 BM
b) [Cu(CN)4]3–      2) Linear and zero
c) [Cu(CN)6]4–

                                 3) Octahedral and zero

d) [Cu(NH)3)4]2+   4) tetrahedral and zero

 
e) [Fe(CN)6]4–      5) octahedral and 1.73BM

 

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a

a-4, b-5, c-2, d-1, e-3

b

a-5, b-4, c-1, d-3, e-2

c

a-1, b-3, c-4, d-2, e-5

d

a-2, b-4, c-5, d-1, e-3


 

answer is A.

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Detailed Solution

Given: Match the following.

Explanation:

a) [Ag(CN)2]- =  Ag+ 3d10  n = 0 u=0 Linear

 

b) [Cu(CN)4]3-  =  Cu+1  3d10 n = 0 u = 0

 

c) [Cu(CN)6]4- Cu+2  3d9   u = 1(1+2 = 1.73

 

d) [Cu(NH)3)4]2+  Cu+2  3d9 sp3 dsp2

 

Hence, the correct option is (A) a-2, b-4, c-5, d-1, e-3.

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