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Q.

Match the metal ions given in Column-I with the spin magnetic moments of the ions given in Column-II and assign the correct code:

 Column-I Column-II
ACo3+I8B.M.
BCr3+II35B.M.
CFe3+III3B.M.
DNi2+IV24B.M.
  V15B.M.

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a

A-IV; B-V; C-II; D-I

b

A-I; B-II; C-III; D-IV 

c

A-IV; B-I; C-II; D-III

d

A-III; B-V; C-I; D-II

answer is A.

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Detailed Solution

CO3+=[Ar]3d6  unpaired e(n)=4 spin magnetic moment (μ)=4(4+2)=24  B.M

Cr3+=[Ar]3d3, unpaired e(n)=3

Spin magnetic moment (μ)

3(3+2)=15B.M

Fe+3[Ar]3d5, unpaired e(n)=5

Spin magnetic moment (μ)=5(5+2)=35B.M

Ni2+=[Ar]3d8, unpaired electron (n)=2

Spin magnetic moment (μ)=2(2+2)=8  B.M

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