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Q.

Match the metal ions given in Column I with the spin magnetic moments of the ions given in Column II and assign the correct code.

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a

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b

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c

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d

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answer is C.

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Detailed Solution

The Fundamental Idea The magnetic moment of spin can be calculated as 

μ=n(n+2)BM

were,μ=Magnetic moment

BM=Bohr Magneton (unit of μ)

n=Number of upaired electrons (e-) in d-orbital.

The electronic arrangement of  CO3+ is [Ar]3d6

Here, n = 4

μ=4(4+2)+24BM

The electronic arrangement of Cr3+ is [Ar]3d3

Here, n = 3

μ=3(3+2)=15BM

The electronic arrangement of  Fe3+ is [Ar]3d5

Here, n = 5

μ=5(5+2)=35BM

The electronic arrangement of Ni2+ is [Ar]3d8

Here, n = 2

μ=2(2+2)=8BM

 

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Match the metal ions given in Column I with the spin magnetic moments of the ions given in Column II and assign the correct code.