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Q.

Match the orbital overlap figures shown in List-I with the description given in List-II and select the correct answer using the code given below the lists.
 

 List - I List - II
P)
Question Image
1)p-d π antibonding
Q)
Question Image
2)d-d σ bonding
R)
Question Image
3)p - d π bonding
S)
Question Image
4)d - d σ bonding

The correct match is
 

 PQRS
1)2134
2)4312
3)2314
4)4132

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a

2

b

1

c

3

d

4

answer is C.

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Detailed Solution

detailed_solution_thumbnail

P  is overlaping of two orbitals of dx2−y2 and is bonding=d-d σ bonding-2

Q is overlap of py and dxy, thus its π overlap and is bonding-p-d π bonding-3

R is overlap of py and dxy, thus its π overlap and is antibonding p-d π bonding-1

S is overlap of dz2 and dx2−y2, thus its σ overlap and is anti-bonding-d-d σ bonding-4

P−2, Q−3, R−1, S−4

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