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Q.

Match the processes in List-I with correct thermodynamic property(ies) in List-II.

 List-I List-II
I)2 moles of  O2(g)  contained in a cylinder at 300K and 5 atm is allowed to expand isothermally against an external pressure of 2 atm in a single step.P)w>0
II)1.5 moles of  He(g)  at 1 atm is compressed reversibly and isothermally at 300 K to 5 atm.Q)ΔU=0
III)5 mol of  N2(g)  is compressed reversibly and adiabatically from 4 L to 1 L.R)ΔH=0
IV)10 moles of  H2O(l)  is converted to ice at its freezing point by cooling it.S)ΔG=0
  T)ΔSsys<0

Choose the correctly matched option:

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a

IS; IIR; IIIQ; IVT

b

IQ; IIT; IIIP; IVS

c

IQ; IIS; IIIS; IVQ

d

IP; IIQ; IIIR; IVS

answer is A.

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Detailed Solution

I – isothermal irreversible expansion
II –isothermal reversible compression
III – adiabatic reversible compression
IV –Liquid  - solid equilibrium at freezing point.

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