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Q.

Match the reaction from column-I with the properties of products from column-II 

 

COLUMN-I

 

 

COLUMN-II

 

I)
Question Image
P)E2 mechanism
II)
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Q)E1and mechanism
III)
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R)E1CB mechanism
IV)
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S)

Products are pair of

Enantiomers.

  T)

Products are pair of

Diastereomers.

 

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a

IPQ, II SR, III RT, IV PQR

b

I R,T, II P,T III Q,S IV PST

c

I RS, II PQ, III RT, IV RST

d

I PQRS, II SRT, IIIRT, IV PQ.

answer is A.

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Detailed Solution

(A) Deuterium incorporation guarantee the EIc.B. Also product show geometrical isomerism (R,T)     (B) Absence of deuterium in product indicates E2 not EI cB. Product show geometrical isomerism (P,T).   
C) In presence of weak base and nucleophile (C2H5OH) and heat, both  SN1 and E1 reaction may take place. There will a pair of enantiomers as substitution products (Q,S)   
D) SN2  And E2 will take place (P, S, T)     
 AR,T;BP,T;CQ,S;DP,S,T.  

 

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