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Q.

Match the reactions in List-I with the features of their products in List-II and choose the correct option.
 

 List-I List-II
(P) (-)-1-Bromo-2-ethylpentane  (single enantiomer) SN2 reaction aqNaOH(1)Inversion of configuration
(Q)(-)-2-Bromopentane (single enantiomer) SN2 reaction  aq. NaOH      (2)Retention of configuration 
(R)(-)-3-Bromo-3-methylhexane (single enantiomer)SN1 reaction  aq. NaOH(3)Mixture of enantiomers
(S)
Question Image

 

(4)Mixture of structural isomers 
  (5)Mixture of diastereomers
 (P)(Q)(R)(S)
(1)1253
(2)2135
(3)1254
(4)2435

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a

2

b

1

c

3

d

4

answer is B.

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Detailed Solution

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a) As chiral carbon is not involved in the reaction, no change in the configuration Q1
(b) Question Image

(c)R→3

(d) Question Image

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