Match the reactions in List-I with the features of their products in List-II and choose the correct option List – I List – IIP)(−)−1−chloro−2−ethylpentane →SN2 reactionaq. NaOH (single enantiomer)1)Retention of configurationQ)(−)−2−chloropentane →SN2 reactionaq. NaOH (single enantiomer)2)Mixture of diastereomersR)(−)−3−chloro−3−methylhexane →SN1 reactionaq. NaOH (single enantiomer)3)Inversion of configurationS)(single enantiomer) →SN1 reactionaq. NaOH4)Mixture of enantiomers 5)Mixture of structural isomers

P → 1 ; Q → 3 ; R → 4 ; S → 2

P → 1 ; Q → 3 ; R → 4 ; S → 2

P → 1 ; Q → 2 ; R → 5 ; S → 3

P → 2 ; Q → 1 ; R → 3 ; S → 5

P → 1 ; Q → 2 ; R → 5 ; S → 4

P → 1 ; Q → 3 ; R → 4 ; S → 2

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Match the reactions in List-I with the features of their products in List-II and choose the correct option
List – I List – II
P) $\begin{array}{l} (-) - 1 - c h l o r o - 2 - e t h y l p e n \tan e \to_{S_{N} 2 r e a c t i o n}^{a q . N a O H} \\ (\sin g l e e n a n t i o m e r) \end{array}$ 1) Retention of configuration
Q) $\begin{array}{l} (-) - 2 - c h l o r o p e n \tan e \to_{S_{N} 2 r e a c t i o n}^{a q . N a O H} \\ (\sin g l e e n a n t i o m e r) \end{array}$ 2) Mixture of diastereomers
R) $\begin{array}{l} (-) - 3 - c h l o r o - 3 - m e t h y l h e x a n e \to_{S_{N} 1 r e a c t i o n}^{a q . N a O H} \\ (\sin g l e e n a n t i o m e r) \end{array}$ 3) Inversion of configuration
S)
$(\sin g l e e n a n t i o m e r)$ $\to_{S_{N} 1 r e a c t i o n}^{a q . N a O H}$
4) Mixture of enantiomers
5) Mixture of structural isomers

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$P \to 1; Q \to 2; R \to 5; S \to 3$

$P \to 2; Q \to 1; R \to 3; S \to 5$

$P \to 1; Q \to 2; R \to 5; S \to 4$

$P \to 1; Q \to 3; R \to 4; S \to 2$

answer is D.

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	List – I		List – II
P)	$\begin{array}{l} (-) - 1 - c h l o r o - 2 - e t h y l p e n \tan e \to_{S_{N} 2 r e a c t i o n}^{a q . N a O H} \\ (\sin g l e e n a n t i o m e r) \end{array}$	1)	Retention of configuration
Q)	$\begin{array}{l} (-) - 2 - c h l o r o p e n \tan e \to_{S_{N} 2 r e a c t i o n}^{a q . N a O H} \\ (\sin g l e e n a n t i o m e r) \end{array}$	2)	Mixture of diastereomers
R)	$\begin{array}{l} (-) - 3 - c h l o r o - 3 - m e t h y l h e x a n e \to_{S_{N} 1 r e a c t i o n}^{a q . N a O H} \\ (\sin g l e e n a n t i o m e r) \end{array}$	3)	Inversion of configuration
S)	$(\sin g l e e n a n t i o m e r)$ $\to_{S_{N} 1 r e a c t i o n}^{a q . N a O H}$	4)	Mixture of enantiomers
		5)	Mixture of structural isomers