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Q.

Match the reactions of metals with dil HNO3 (in List I) with the products (in List II).

 List I                                                                                List II         (1) Mg + very dil. HNO3                                           (i) NO  (2) Zn + dil. HNO3                                                     (ii) H2 (3) Sn + dil. HNO3                                                     (iii) N2O  (4) Pb + dil. HNO3                                                     (iv) NH4NO3

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a

1         2          3           4 (i)       (iii)        (ii)        (iv)

b

1           2         3        4 (ii)       (iv)      (iii)      (i)

c

1           2          3          4 (ii)       (iii)        (iv)      (i)

d

1           2           3           4 (iii)        (i)        (iv)         (ii)

answer is B.

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Detailed Solution

Mg reacts with dilute HNO3 to form Mg(NO3)2 and hydrogen gas.

Mg+2HNO3Mg(NO3)2+H2

Zn reacts with dilute HNO3 and gives Zn(NO3)2, N2O and water.

4Zn+10HNO34Zn(NO3)2+N2O+5H2O

Sn reacts with dilute HNO3 and forms Sn(NO3)2, NH4NO3, and water.

4Sn+10HNO34Sn(NO3)2+NH4NO3+3H2O

Pb reacts with dilute HNO3 and forms Pb(NO3)2, NO, and water.

3 Pb + 8 HNO3  3Pb(NO3)2 + 2NO + 4H2O

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