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Q.

Match the reagent given in column A with its reaction given in column B 

 Column A Column B
i)Conc. H2SO4 /160 -1700CA)Dehydrogenation of alcohols
ii)Alcoholic KOHB)Dehalogenation of dihalides
iii)Cu / 3000CC)Dehydration of alcohols
iv)Zn / alcoholD)Dehydrohalogenation of alkyl halides
 (i)(ii)(iii)(iv)
1)ABCD
2)CDAB
3)CDBA
4)DABC

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a

2

b

1

c

3

d

4

answer is B.

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Detailed Solution

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i) Conc. H2SO4/1601700is dehydration of alcohols
Ex : CH3CH2OH160-170°C Cons: H2SO4CH2=CH2+H2O
ii) Alcoholic KOH is used in dehydrohalogenation
Ex : CH3CH2Cl alc.KOHCH2=CH2+KCl+H2O
iii) Cu / 3000C is used in dehydrogenation
Ex : CH3CH2OH300CCUCH3CHO+H2
iv) Zn / alcohol is used in dehalogenation
Ex : CH2ClCH2ClZn/ alcoholCH2=CH2+ZnCl2 

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