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Q.

Match the species in Column-I with their related properties in Column-II

 Column - I Column - I
i)N 7p)Paramagnetic
ii)Co2+27q)Coloured ion
iii)Mn2+25r)Sum of spin 32
iv)Fe2+26s)Magnetic moment24 B,M

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a

i - p,r  ,   ii - q,s  ,  iii - r,s  ,  iv - p,r,s

b

i - p  ,   ii - q,r  ,  iii - p,s  ,  iv - s

c

i - p,r  ,   ii - p,q,r  ,  iii - p,q  ,  iv - p,q,s

d

i - r  ,   ii - s  ,  iii - r,s  ,  iv - p,s

answer is C.

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Detailed Solution

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cN7=1S22S22P3

Question Image

 

 

Paramagnetic due to unpaired electron and sum of spin

=3×12=1.5

Thus, ip,r

Co27=Ar Question Image

Co2+=Ar   Question Image

Paramagentic and coloured due to unpaired sum of spin =1.5

Thus, (ii)p,q,r

Mn25=Ar4S2  3d6  Question Image

Mn2+25ArS23d5     Question Image

Coloured and aparamagentic

Sum of spin =2.5

Thus, iiip,q

Fe26=Ar4S23d6 Question Image

Fe2+26=Ar3d6   Question Image

Colored and Paramagnetic

Sum of spin =2.0

Magnetic moment =nn+2

 =46

=24BM

Thus, (iv) p,q,s 

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