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Q.

Match the species/molecules listed in Column-I with their characteristics listed in Column-II.

 Column-I Column-II
aClF5,BrF4+,IF6pAll molecule/ions are polar in nature
bClF3,BrF2+,ICl4qAIl molecules/ions have same number of lone pair(s) and same shape
cXeF2,ICl2,I3rAll molecules/ions have same oxidation stale of central atoms
dClOF3,ClF4+,IO2F2sAll molecules/ions have same hybndization of central atoms

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a

(a-p, r); (b-r,q); (c-q); (d-p, q, r, s)

b

(a-p, r); (b-r); (c-q, s); (d-p, q, r, s)

c

(a-p); (b-r); (c-q, s); (d-p, q, r, s)

d

(a-p, r); (b-r); (c-q, s); (d-p, r, s)

answer is A.

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Detailed Solution

The molecular geometry of ClF5 are square pyramidal with asymmetric charge distribution around the central atom. Therefore this molecule is polar. Here the oxidation state is same in all the three which is +7.
The oxidation state is same in all the three ,molecules of option 2, which is +7. The molecular geometry of the molecules in the option 3 is linear.

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