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Q.

Match the terms given in Column I with the items given in Column II.

 Column I Column II
A.Λm1.Intensive property
B.Ecell 2.Depends on number of ions/volume
C.K3.Extensive property
D.ΔrGcell 4.Increases with dilution

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a

A - 1 ; B - 4 ; C - 3 ; D - 2

b

A - 1 ; B - 4 ; C - 2 ; D - 3

c

A - 4 ; B - 1 ; C - 3 ; D - 2

d

A - 4 ; B - 1 ; C - 2 ; D - 3

answer is D.

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Detailed Solution

 A.  (4)   B. (1)  C. (2)  D. (3)
A. Λm (molar conductivity) is the conductivity due to number of ions furnished by one mole of electrolyte. As dilution increases, number of ions present in the solution increases hence. molar conductivity increases.
B.Ecell of any atom/ion does not depend upon number of atom/ion, hence Ecello of any atom/ion is an intensive property.
C. K represents specific conductivity which depends upon number of ions present in per unit volume. 
D. ΔrGcell  is an extensive property as it depends upon number of particles(species).

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