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Q.

Match the values of 1st and 2nd ionisation energy and electron gain enthalpy given in the column-I with types of elements/compounds given in column-II.

Δ1H1, Δ1H2,ΔegH in kJmol1

  Colamn-I Colamn-II
(a)2372 5251 -48(p)Element which exists as a strong reducing agent
(b)1419 3051 - 49(q)Element which exists as a monoatomic molecule
(c)1681 3051 -49(r)Least reactive non-metal
(d)1008 1846 -295(s)Element which acts as a strong oxidising agent
  (t)Element whose oxide is strongly basic in nature.

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a

(a-p), (b-q, t). (c-r), (d-t)

b

(a-q), (b-p, t). (c-s), (d-r)

c

(a-p), (b-p, s). (c-q), (d-t)

d

(a-t), (b-p, t). (c-r), (d-r)

answer is A.

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Detailed Solution

The noble gases exist as monatomic elements with values,

Δ1H1=2372 Δ1H2=5251,,ΔegH=-48 in kJmol1

For instance, the strongest common oxidising agent is elemental fluorine with values,

Δ1H1=1681 Δ1H2=3374,,ΔegH=-333 in kJmol1

Helium is the least reactive of the non-metallic elements with values,

Δ1H1=1008 Δ1H2=1846,ΔegH=-295 in kJmol1

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