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Q.

Mechanism of a hypothetical reaction
X2+Y22XYis given below :

(i) X2X+X(fast)

(ii)  X+Y2XY+Y (slow)

(iii) X + Y ➔ XY (fast)

The overall order of the reaction will be

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a

2

b

0

c

1.5

d

1

answer is C.

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Detailed Solution

Note : Correct the reactions given in question as 

X2X+X                   (fast) X+Y2XY+Y          (Slow)  Slow step is the rate determining step.   Rate =K[X]Y2             (i)  Equilibrium constant for fast step, K=[X]2X2 [X]=KX2  By substituting [X] in equation (i), we get   Rate =kKX2Y2=k'X21/2Y2  Order of reaction =12+1=32=1.5

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