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Q.

Mechanism of a hypothetical reaction,

 X2+Y22XY  is  given  as

i .X2X+Xfast

ii. X+Y2XY+Yslow

iii. X+YXYfast

False statement about order is

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a

Overall order is 1.5        

b

Order w.r.t X2is 0.5

c

order w.r.t  Y  is 0.5

d

order w.r.t  is Y2 is 1

answer is C.

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Detailed Solution

For equation (1)

Keq=X2X2

X=Keq12X212(1)

Rate law (for slow step)

Rate = KXY2

Substituting the value of  X from (1)

rate  =  KKeq12X212Y2

orderw.r.t  X2=12

order  w.r.t  Y2=1

Overall order = 1.5

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