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Q.

MeCH(CN)CO aq. H2SO4ΔP

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a

P giving +ve iodoform test and -ve test with Fehling solution.

b

P giving -ve iodoform test and +ve test with NaHCO3 solution..

c

P gives +ve Lucas test and -ve test withNaHCO3 solution.

d

P gives +ve test with NaHCO3 and cerric ammonium nitrate solut.

answer is A.

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Detailed Solution

MeCH(CN)CO aq. H2SO4ΔP

P giving +ve iodoform test and -ve test with Fehling solution.

Aldehydes and ketones are two different categories for aldehydes. The aldehydes have the ability to diminish Tollen's reagent or Fehling's solution as well as provide a positive iodoform test result. Although the ketones cannot decrease Tollen's reagent or Fehling's solution, they can produce a positive Iodoform test result.

 

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