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Q.

Melting point of any solid depends on pressure as 

P2P1=ΔHfusion V1VSlnT2T1
Calculate freezing point of water (in C° ) at a pressure of 1001 bar if freezing point of water at 1 bar is 0°C. Molar volume of ice and liquid water is 19 mL and 18 mL respectively and increase in enthalpy due to melting is 6600J/ mole .

[In 0.975=0.025]

[Instruction : Neglect sign of the temperature, therefore if your answer is 8.65C, express answer as 9]

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answer is 7.

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Detailed Solution

we have 

(10011)×100 

=6000(1819.65)×103lnT2273

T2=265.59K or 7.4C

freezing point of water is 7 °C

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