Q.

Metal deficiency defect is shown by Fe0.93O .In the crystal , some Fe+2 cations are missing and loss of positive charge is compensated by the presence of Fe+3 ions . The percentage of  Fe+2 ions in the  Fe0.93O crystals is-

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answer is 85.

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Detailed Solution

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LetFe+2=x,thenFe+3=0.93x

2x+3(0.93-x)=2

x=0.79

% ofFe+2=0.790.93×100=85

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