Q.

Mixture of volatile components A and B has total vapour pressure (in torr)  p  = 254 — 119 XA where XA is mole fraction of A in mixture. Hence pAo and pBo are (in torr)

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a

119, 373

b

254, 119

c

119, 254

d

135, 254

answer is C.

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Detailed Solution

P=XAPA0+XBPB0    =(PA0-PB0)XA+PB0    =PB0 +  (PA0-PB0)XA  So,   PBo=  254

PAo-PBo=-119

PA0=135

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