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Mixture(s) showing positive deviation from Raoult’s law at 35°C is (are)

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carbon tetrachloride+methanol

carbon disulphide+acetone

benzene+toluene

phenol+aniline

answer is A.

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Detailed Solution

(A) CCl₄+CH₃OH⇒ Positive deviation from Raoult's law.

Here, H- bonding in methanol is broken by CCl₄.

(B) Mixing of polar and non-polar liquids will produce a solution of weaker interaction, resulting in positive deviation for the mixture of carbon disulphide and acetone.

(D) Stronger H-bonding is formed in the mixture oof phenol and aniline, leading to negative deviation.

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