Q.

Mn(CO)4NO is diamagnetic because :

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a

Mn is in + 1 oxidation state in this complex

b

Mn metal is diamagnetic in free state

c

NO is present as positive ligand

d

All of the above

answer is C.

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Detailed Solution

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Mn(CO)+14NO:Paramagnetic due to presence of unpaired es in NO Mn(CO)4NO+:No unpaired eeither on ligands or on Mn hence it is diamagnetic 

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