Q.

MnO2 when fused with KOH and oxidised in air gives a dark green compound X

In acidic solution,X undergoes disproportionation to give an intense purple colour 

compound Y and MnO2. The compound X and Y respectively, are

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a

K2MnO4 and KMnO4

b

K2MnO4and Mn2O7

c

Mn2O7 and KMnO4

d

KMnO4 and K2MnO4

answer is A.

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Detailed Solution

2MnO2+4KOH+O2Oxidised in air     2K2MnO4XDark green compound+2H2O

          3Mn+6O4-2+4H+Disproportionation2Mn+7O4-YPurple compound+Mn+2O2+2H2O

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