Q.

Molar conductance of 0.1 M acetic acid is 7 ohm1 cm2 mol1. If the molar conductance of acetic acid at infinite dilution is 380.8 ohm1 cm2 mol1, the value of dissociation constant will be: 

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a

1.66×103 mol dm1

b

226×105 mol dm3

c

3.38×105 mol dm3

d

1.66×102 mol dm3

answer is D.

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Detailed Solution

Ka=2=0.1×(7380.8)2=3.38×105

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Molar conductance of 0.1 M acetic acid is 7 ohm−1 cm2 mol−1. If the molar conductance of acetic acid at infinite dilution is 380.8 ohm−1 cm2 mol−1, the value of dissociation constant will be: