Q.

Molar conductivity (Λm°) at infinite dilution of NaCl, HCl and CH3COONa are 126.4, 425.9 and 91.0 S cm2mol1 respectively (Λm°) for CH3COOH  will be

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a

425.5  Scm2mol1

b

180.5  Scm2mol1

c

290.8  Scm2mol1

d

390.5  Scm2mol1

answer is D.

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Detailed Solution

ΛNaCl°=126.4Scm2mol1

ΛHCl°=425.9  Scm2  mol1

ΛCH3COONa°=91.0  Scm2  mol1

ΛCH3COOH°=ΛCH3COONa°+ΛHCl°ΛNaCl°                              =91.0+425.9  126.4                              =390.5  cm2mol1

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