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Q.

Molar conductivity of different aqueous solutions of KCl at the same temperature are given below.

Solution Molar conductivity
0.1 mole KCl present in 100 ml solutionX
0.2 mole KCl present in 200 ml solutionY
0.5 mole KCl present in 500 ml solutionZ

The correct order of molar conductivity at the same temperature is 

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a

X > Y > Z 

b

X = Y = Z 

c

X > Z > Y

d

Z > Y > X

answer is B.

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Detailed Solution

Molarity is the same and molar conductivity is the same.

λm=1000κM

0.1 mole KCl present in 100 ml solution = 1 M

0.2 mole KCl present in 200 ml solution = 1 M

0.5 mole KCl present in 500 ml solution = 1 M

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