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Q.

Molar enthalpy of combustion of C2H2(g),C,graphite and H2(g) are 1300,394 and 286 kJ/mole respectively, then, calculate Bond enthalpy of CC bond in kJ/mole :

Given : ΔHsub Cgraphite =715kJ/ mole 

ΔHBE(H-H)=436 kJ/mole

ΔHBE(C-H)=413 kJ/mole

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a

415

b

610

c

1215

d

814

answer is D.

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Detailed Solution

2C(gr)+H2(g)C2H2(g)

ΔHRxn=394×2286+1300=226

226=2×715+4362×413x

x=814

Hence, option D is correct.

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Molar enthalpy of combustion of C2H2(g),C,graphite and H2(g) are −1300,−394 and −286 kJ/mole respectively, then, calculate Bond enthalpy of C≡C bond in kJ/mole :Given : ΔHsub Cgraphite =715kJ/ mole ΔHBE(H-H)=436 kJ/moleΔHBE(C-H)=413 kJ/mole