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Q.

Molar heat of vaporization of a liquid is 6kJmol1 if the entropy change is16Jmol1K1, the boiling point of the  liquid is 

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a

102°C

b

375K 

c

273K

d

375°C 

answer is B.

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Detailed Solution

Since boiling occurs at equilibrium conditions, so ΔG=0

Now, T =HS
T = 6000J/mol16 J/mol/K
T = 375K
Hence, the boiling point of the liquid is 375 K.

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