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Q.

Molecular weight of Mohr's salt is 392 . Its equivalent weight when it is oxidised by KMnO4 in acidic medium is

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a

392

b

196

c

130.6

d

78.5

answer is A.

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Detailed Solution

We know that formula for Mohr's salt is FeSO4(NH4)2SO46H2O

And the reaction between Mohr's salt and acidified KMnO4 is

2KMnO4+10FeSO4(NH4)2SO46H2O+8H2SO4K2SO4+2MnSO4 +10(NH4)2SO4+2Fe2(SO4)3+8H2O  

Here, the Net valence=1

And, we know that equivalent weight=Molecular WeightNet positive valence

So, the equivalent weight Mohr's salt=3921

Hence, option(a) is the answer.

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