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Q.

Molecule AB has a bond length of 1.617A0 and a dipole moment of 0.38 D. The fractional charge on each atom (absolute magnitude) is (e0= 4.802 × 10–10 esu)

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a

0

b

0.05

c

0.5

d

1.0

answer is B.

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Detailed Solution

μ=dxδ
0.38 x 10-18 =1.617 x 10-8cm x δ
δ=0.38×10-18 esu cm1.617×10-8 cm=0.235esu×10-10

4.802 x 10-10 esu ------100% ionic
0.235x10-10esu  -------?
0.235×10-10 esu cm4.802×10-10 cm×100=0.048×100=4.8%

= 0.05

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