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Q.

Molecules in which bond angle increases due to back bonding are:

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a

BF3

b

OSiH32

c

NSiH33

d

CH3NCS

answer is B, C.

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Detailed Solution

Molecules is bond angle increases due to back bonding are OSiH32 and NSiH33.

Although it is unclear, based on what I understand, I believe have more bond

angle because of presence of only one lone pair while on O(Sih3)2 two lone pair are present so due to repulsion (SIH3) come nearer to each other and bond angle get decrease on O(SiH3)2.

So, N(SiH3)3 have more bond angle.

Hence option B and C is correct.

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