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Q.

Molten Ni(NO3)2 is electrolysed between platinum electrodes using 0.1 Faraday of electrical charge. The number of moles of Nickel deposited at the cathode  is

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a

 0.10

b

0.05

c

 0.15

d

0.20

answer is C.

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Detailed Solution

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Each NI+2 ion accepts 2 electrons during its reduction

 So, g eq wt of Ni=Mass of one mole of NiNo. of e-1 accepted by each Ni2+ ion =2 i.e., No.of g eq is twice No.of mole  No. of mole=No. of g eq2 0.1 Faraday of charge deposits 0.1 g eq of substance or 0.12=0.05 mole

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