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Most reactive towards Aromatic Aromatic Electrophillic .Substitution.Reaction

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a

Benzene

b

Chloro Benzene

c

Phenyl Acetate

d

Nitro Benzene

answer is C.

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Detailed Solution

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${CH}_{3} {COO}^{-}$ is EDG,increases the electron density in the ring,hence reactivity wrt electrophile increases,hence EDG's are acting as ring activators
-Cl, -NO₂ groups are EWG's,decreases the electron density in the ring.hence the attraction of electrophile by the ring decreases,therefore reactivity of ring wrt electrophile decreases,hence EWG's are called as ring deactivators.
Electron withdrawing power order: $- {NO}_{2} > - Cl$
$- {NO}_{2}$ is strong deactivator,hence nitrobenzene reactivity wrt electrophile is least.
EDG means electron donating group.

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