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Most soluble and thermally most stable alkaline earth metal sulphates are respectively

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${CaSO}_{4}, {BaSO}_{4}$

${MgSO}_{4}, {CaSO}_{4}$

${BaSO}_{4}, {MgSO}_{4}$

${BeSO}_{4}, {BaSO}_{4}$

answer is D.

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Detailed Solution

The solubility of alkaline metal carbonates and sulphates decreases with decrease in hydration energy as we move down the group.

On moving down the group, the electropositive character and the thermal stability of alkaline earth metal sulphates increases.

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