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Q.

Most stable carbocation formed from (CH₃)₃C – Br, (C₆H₅)₃CBr, (C₆H₅)₂CHBr and C₆H₅CH₂Br would be

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a

${({CH}_{3})}_{3} \overset{\oplus}{C}$

b

$C_{6} H_{5} {C \overset{\oplus}{H}}_{2}$

c

${(C_{6} H_{5})}_{3} \overset{\oplus}{C}$

d

${(C_{6} H_{5})}_{2} C \overset{\oplus}{H}$

answer is C.

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Detailed Solution

$\begin{aligned} {(C_{6} H_{5})}_{3} C^{+} > {(C_{6} H_{5})}_{2} {HC}^{+} > {({CH}_{3})}_{3} C^{+} \\ > (C_{6} H_{5}) {CH}_{2}^{+} \end{aligned}$

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Most stable carbocation formed from (CH3)3C – Br, (C6H5)3CBr, (C6H5)2CHBr and C6H5CH2Br would be