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Q.

Most volatile hydride of VIA group is

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a

H2O

b

H2Se

c

H2S

d

H2Te

answer is A.

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Detailed Solution

  • From H2O to H2Po vanderwaal's forces of attractions increases .
  • B.P order must be
  • H2O< H2S < H2Se < H2Te

But due to association of H2O molecules through intermolecular H- bonding it has abnormal B.P

Actual B.P order is:    H2S < H2Se < H2Te < H2O

order of Volatility:   H2S > H2Se > H2Te > H2O

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