Q.

n – Butane is treated with chlorine at 250C. The percentage of 1-Chlorobutane formed is (x – 0.2) x 10. The x is

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answer is C.

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Detailed Solution

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At room temp, the relative rates of abstraction of hydrogenations are 5 : 3.8 : 1

                1-chlorobutane2-chlorobutane=No.of10-HNo.of20-Hxreactivityof10Hreactivityof20H=64x13.8=615.2

% of 1 – chlorobutane = 621.2x100=28.3%

[x – 0.2] 10 = [3 – 0.2] 10 = 28 % [nearly]

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