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Q.

n moles of an ideal gas is taken through a four step cyclic process as shown in the diagram. Calculate work done by the gas in a cycle in terms of temperatures T1, T2, T3 and T4.

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a

nRT3+T2T4+T1

b

nRT3T2T4+T1

c

nRT3+T2+T4+T1

d

nRT3T2T4-T1

answer is B.

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Detailed Solution

Process 1 – 2 and 3 – 4 are isochoric process.
 W12 = W34 = 0
2 – 3 and 4 – 1 are isobaric processes.
W23=P2ΔV=P2V3P2V2=nRT3nRT2=nRT3T2W41=P1ΔV=P1V1P1V4=nRT1T4=nRT4T1W=nRT3T2T4+T1

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