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Q.

n moles of an ideal gas undergo a process A and B as shown in the figure. The maximum temperature of the gas during the process will be

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a

32p0V0nR

b

94p0V0nR

c

92p0V0nR

d

9p0V0nR

answer is A.

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Detailed Solution

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As, T will be maximum temperature where product of pV is maximum 

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Equation of line AB, we have

YY1=Y2Y1X2X1XX1pp0=2p0p0v02v0V2V0pp0=p0V0V2V0p=p0V0V+3p0pV=p0V0V2+3p0VnRT=p0V0V2+3p0VT=1nRp0V0V2+3p0V

For maximum temperature,

TV=0p0V0(2V)+3p0=0p0V0(2V)=3p0V=32V0

(condition for maximum temperature) Thus, the maximum temperature of the gas during the process will be

Tmax=1nRp0V0×94V02+3p0×32V0=1nR94p0V0+92p0V0=94p0V0nR

Alternate solution

Since, initial and final temperature are equal, hence maximum temperature is at the middle of line.

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i.e. pV=nRT=32p03V02nR

Tmax9poV04nR

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