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Q.

N-N single bond enthalpy is 'X'  N=N double bond enthalpy is 'Y' correct relation is

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a

2X > Y

b

2X < Y

c

2X = Y

d

2Y = X

answer is B.

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Detailed Solution

N∙∙-N∙∙

sigma bond is very weak due to the repulsions between the adjacent nitrogen atoms

  âˆ´ 'X' has very low magnitude

A double bond contains one sigma (strong) and a Pi-bond(weak)

So  Sum of enthalpies of two sigma bonds > Enthalpy of a Double bond

But in the case of Nitrogen

Sum of enthalpies of two sigma bonds (2X)< Enthalpy of a Double bond(Y)

                2X < Y

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