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Q.

N2 and  O2 are converted to monocations N2+ and O2+ respectively, which is wrong statement?

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a

In N2+, the NN bond weakens 

b

In O2+, the OO bond order increase

c

In O2+, the paramagnetism decrease

d

N2+ become diamagnetic

answer is D.

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Detailed Solution

Bond order =1/2×NBNAB

Order of filling MO is:

1   N2: 

valence electrons  =5+5=10
(σ2s)2(σ2s)2(σ2p)2(π2p)4BO=1/2×(60)=3

2   N+2:
valence electrons  =5+5-1=9

BO=1/2×(50)=2.53O2:

valence electrons  =6+6=12

(σ2s)2(σ2s)2(σ2p)2(π2p)4π2p2BO=1/2×(62)=2

3    O2+:

valence electrons =6+6-1=11

(σ2s)2(σ2s)2(σ2p)2(π2p)4π2p1BO=1/2×(61)=2.5

Bond strength   bond order

bond strength/order N2>N2+ and  O2+>O2 

N2+ is paramagnetic with one unpaired e-

Hence correct option is D. 

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