Q.

Name the product(s) formed during the reaction of primary aliphatic amines with nitrous acid at room temperature?

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a

RN2+Cl-

b

ROH

c

Both (a) and (b)

d

None of the above

answer is C.

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Detailed Solution

Primary aliphatic amines react with nitrous acid to form aliphatic diazonium salts which being unstable, forms alcohol and liberate nitrogen gas quantitatively.
R-NH2 + HNO2NaNO2+HClRN2+Cl-H2OROH+N2+HCI

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