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Q.

NH35CoOOCoNH354+S2O82 oxidise NH35CoOOCoNH355+

The magnetic moment of the green complex is 1. 7 BM and for brown complexes magnetic moment is zero. (0-0) is the same in all respect in both complexes. The oxidation state of Co in brown complex and green complex respectively are :

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a

III II  brownand III III green

b

III III brownand III II green

c

III IIIbrown  and IV III green 

d

III IV brown and III III green

answer is A.

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Detailed Solution

Since III is brown while the IV is green as a result option A is correct.

Hence, the correct option is A.

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