${NH}_{4}^{+}$ is kept in group zero in salt analysis table,because

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The $K_{s p}$ of salts of ammonium is high

Ammonium salts are insoluble in water

$K_{s p}$ of salts of ${NH}_{4}^{+}$ are low

Its salts are highly soluble in water

answer is A, B.

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Detailed Solution

(a) and (b) are correct because ${NH}_{4}^{+}$ salts are ionic and can form H-bonds with water, therefore they are highly soluble in water. Higher the solubility, higher will be $K_{s p}$ .

$∴$ (c) and (d) are not correct.

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