Q.

[Ni(H2O)6](aq)2+1  mole(P)+1mole  en(aq)Q+1mole  en(aq)R+1mole  en(aq)S

When – en is Ethane –1,2 –diamine
Correct statement(s) about these complexes is/are
 

see full answer

Start JEE / NEET / Foundation preparation at rupees 99/day !!

21% of IItians & 23% of AIIMS delhi doctors are from Sri Chaitanya institute !!
An Intiative by Sri Chaitanya

a

‘R’ can exhibit geometrical isomerism and both have same colour.

b

In P,Q,R and S hybridization of nickel is same.

c

P,Q,R and S are high spin complexes.

d

For the complex ‘S’ totally two stereo isomers possible.

answer is B, D.

(Unlock A.I Detailed Solution for FREE)

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Detailed Solution

P:[Ni(H2O)6]green2+   Q:[Ni(H2O)4(en)]pale  blue2+               R:[Ni(H2O)2(en)2]blue/purple2+

S:[Ni(en)3]violet2+

Question Image

For the Octahedral complexes of Ni2+ only one electronic configuration possible. Hence, high spin and low spin complexes words not suitable.
D) [Ni(en)3]2+  geometrical isomerism not possible but optical isomerism possible.
 

Watch 3-min video & get full concept clarity
score_test_img

Get Expert Academic Guidance – Connect with a Counselor Today!

whats app icon
[Ni(H2O)6](aq)2+1  mole(P)→+1mole  en(aq)Q→+1mole  en(aq)R→+1mole  en(aq)SWhen – en is Ethane –1,2 –diamineCorrect statement(s) about these complexes is/are