Q.

Nickel complex is represented as NiCl2.2KCl. Oxidation state of Ni in this complex is

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a

+6

b

0

c

+4

d

+2

answer is B.

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Detailed Solution

complex is K2[NiCl4] which is also represented as [NiCl4]2-. Oxidation state of Ni  in [NiCl4]2- is:

Oxidation state of Ni+4(Oxidation state of Cl)=-2 Oxidation state of Ni+4(-1)=-2 Oxidation state of Ni=+2

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