Q.

Nitration of aniline by HNO3+H2SO4 mixture gives 51% para nitro derivative while 47% is meta nitro derivative and rest 2% ortho nitro derivative at 15° C. In order to obtain 276 gm of p-nitro aniline what minimum mass of aniline should be taken?

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a

563.3 gm 

b

364.7 gm 

c

476.7 gm

d

514.2 gm 

answer is C.

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Detailed Solution

The structure is,

Question Image

W=276138×10.51×93 W=364.7 g

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